Study of Alkaline Electrodes for Hybrid Polymer Electrolyte Fuel Cells
نویسندگان
چکیده
Hybrid polymer electrolyte fuel cells combine a proton exchange membrane PEM and anion exchange membrane AEM and exhibit unique advantages. The electrochemical performance and current limitations of a hybrid cell with an alkaline electrode fabricated on a Nafion membrane was characterized at 70°C as a function of relative humidity. To separate the individual characteristics of the AEM anode and cathode electrodes, two semihybrid cell configurations, each with an AEM and PEM electrode, were constructed and compared to a conventional PEM fuel cell. Electrochemical impedance spectroscopy was used to diagnose the cell component characteristics. In particular, low catalyst utilization in the AEM electrode was a primary factor in the performance losses in the hybrid cells. © 2010 The Electrochemical Society. DOI: 10.1149/1.3468700 All rights reserved.
منابع مشابه
An Experimental Study on the Placement of Reference Electrodes in Alkaline Polymer Electrolyte Membrane Fuel Cells
The ability to accurately measure separate in situ anode and cathode overpotentials and impedance responses is still a source of debate when investigating fuel cells of planar configuration containing < 100 μm thickness solid electrolytes and when using the common three electrode arrangement. The results obtained in this study indicate that the overpotentials and impedances of the anode and cat...
متن کاملSynthesized Bimetallic Electrocatalyst for Oxygen Reduction Reaction in Polymer Electrolyte Fuel Cells
In the present study, a step by step process was applied to synthesize bimetallic electrocatalyst (Ru and Pt on VulcanXC-72R). This process can reduce the amount of platinum and increase the gas diffusion electrode (GDE) performance in the cathodic reaction of polymer electrolyte membrane fuel cells (PEMFCs). Using the impregnation by hydrothermal synthesis method, a series of electrocatalysts ...
متن کاملNumerical analysis of reactant transport in the novel tubular polymer electrolyte membrane fuel cells
In present work, numerical analysis of three novel PEM fuel cells with tubular geometry was conducted. Tree different cross section was considered for PEM, namely: circular, square and triangular. Similar boundary and operational conditions is applied for all the geometries. At first, the obtained polarization curve for basic architecture fuel cells was validated with experimental data and then...
متن کاملStudy of flow and heat transfer characteristics in a periodic zigzag channel for cooling of polymer electrolyte fuel cells
In this study, a periodic zigzag channel with rectangular cross-section has been used in order to obtain a high-efficiency system for cooling a polymer electrolyte fuel cell. An appropriate function of fuel cells and enhancement of their lifetime require uniform temperature conditions of around 80°C. On the other hand, due to volume and weight constraints, a low-density compact heat exchanger i...
متن کاملExperimental Study on a 1000W Dead-End H2/O2 PEM Fuel Cell Stack with Cascade Type for Improving Fuel Utilization
Proton exchange membrane fuel cells (PEMFCs) with a dead-ended anode and cathode can obtain high hydrogen and oxygen utilization by a comparatively simple system. Nevertheless, the accumulation of the water in the anode and cathode channels might cause a local fuel starvation degrading the performance and durability of PEMFCs. In this study, a brand new design for a polymer electrolyte membrane...
متن کامل